张博生

张博生，博士，副教授，硕士生导师。2020年6月毕业于兰州大学功能有机分子化学国家重点实验室，获理学博士学位（导师：梁永民 教授）；同年入职西北师范大学化学化工学院。从事过渡金属催化和有机方法学研究，在Catellani反应和自由基反应研究中取得了一系列成果，发表学术论文二十篇余篇。其中，以第一作者和通讯作者在J. Am. Chem. Soc., ACS Catal., Org. Lett.，Chem. Commun., Org. Chem. Front.等重要学术期刊发表SCI论文十余篇，其中有三篇被国际著名评述杂志《Synfact》选为亮点并作重要评论。Web of Science个人H因子为19。

2023

34. Combined C-H amination and intermolecular alkyne insertion for a three-component cyclization.

Zhang, B.-S.*; Yang, Y.-X.; Oliveira, J. C. A.; Zhang, Z.-Q.; Warratz, S.; Wang, Y.-M.; Li, S.-X.; Wang, X.-C.; Gou, X.-Y.; Liang, Y.-M.; Quan, Z.-J.*; Ackermann, L*. 

Cell Rep. Phys. Sci. 2023, 101647. 

33. Template Synthesis to Solve the Unreachable Ortho C–H Functionalization Reaction of Aryl Iodide. 

Zhang, B.-S.*; Jia, W.-Y.; Wang, Y.-M.; Oliveira, J. C. A.; Warratz, S.; Zhang, Z.-Q.; Gou, X.-Y.; Liang, Y.-M.; Wang, X.-C.; Quan, Z.-J.*; Ackermann, L.*

J. Org. Chem. 2023. 10.1021/acs.joc.3c02014.

32. Synthesis of C-Aryl Glycosides by C−H Functionalization.

Gou, X.-Y.; Zhu, X.-Y.; Zhang, B.-S.*; Liang, Y.-M.*

Chem. Eur. J. 2023, 29 (32), e202203351.

31. Synthesis of C4-Aminated Carbazoles and Their Derivatives via Pd/NBE Chemistry.

Zhang, B.-S.*; Zhao, S.-Y.; Li, S.-X.; Jia, W.-Y.; Yang, Y.-X.; Wang, Y.-M.; Gou, X.-Y.; Liang, Y.-M.; Wang, X.-C.*; Quan, Z.-J.*

J. Org. Chem. 2023, 88 (3), 1786-1795.

2022

30. Synthesis of C8-Aminated Pyrrolo-Phenanthridines or -Indoles via Series C(sp2 or sp3)–H Activation and Fluorescence Study

Zhang, B.-S.*#; Jia, W.-Y.#; Gou, X.-Y.; Yang, Y.-H.; Wang, F.; Wang, Y.-M.; Wang, X.-C.*; Quan, Z.-J.*

Org. Lett. 2022, 24 (11), 2104-2109.

Hightlighted by Synfacts.

29. Visible light-promoted intermolecular cyclization/aromatization of chalcones and 2-mercaptobenzimidazoles via an EDA complex and a mechanism study.

Zhao, X.-J.; Li, Y.; Li, M.; Tian, Y.-L.; Wang, W.-P.; Zhang, B.-S.*; Wang, X.-C.*

Org. Biomol. Chem. 2022, 20 (25), 5139-5144.

28. Ortho C–H Hydroxyalkylation or Methylation of Aryl Iodides by Ethers and TMSI via a Catellani Strategy.

Zhang, Z.; Chen, X.; Li, X.-S.; Wang, C.-T.; Niu, Z.-J.; Zhang, B.-S.; Liu, X.-Y.*; Liang, Y.-M.*

Org. Lett. 2022, 24 (38), 6897-6902.

27. Ruthenium-Catalyzed Stereo- and Site-Selective ortho- and meta-C−H Glycosylation and Mechanistic Studies.

Gou, X.-Y.; Li, Y.; Shi, W.-Y.; Luan, Y.-Y.; Ding, Y.-N.; An, Y.; Huang, Y.-C.; Zhang, B.-S.; Liu, X.-Y.*; Liang, Y.-M.*

Angew. Chem. Int. Ed. 2022, 61 (32), e202205656.

26. Visible light promoted polyhalomethylation of alkenes: alkylation and cyclization

Wang, T.-L.; Zhang, B.-S.; Liu, J.-J.; Liu, X.-J.; Wang, X.-C.*; Quan, Z.-J.*

Org. Chem. Front. 2022, 9 (4), 1004-1009.

2021

25. Palladium-Catalyzed Synthesis of Tricyclic Indoles via a N–S Bond Cleavage Strategy

Zhang, B.-S.*#; Wang, F.#; Gou, X.-Y.; Yang, Y.-H.; Jia, W.-Y.; Liang, Y.-M.*; Wang, X.-C.; Li, Y.*; Quan, Z.-J.*

Org. Lett. 2021, 23 (19), 7518–7523.

24. Palladium Catalyzed C-H Glycosylation and Retro Diels-Alder Tandem Reaction via Structurally Modified Norbornadiene (smNBDs)

An, Y.#; Zhang, B.-S.#; Ding, Y.-N.; Zhang, Z.; Gou, X.-Y.; Li, X.-S.; Wang, X.; Li, Y.*; Liang, Y.-M.*

Chem. Sci. 2021, 12, 13144-13150.

23. Experimental and Computational Studies of Palladium-Catalyzed Spirocyclization via a Narasaka–Heck/C(sp3 or sp2)–H Activation Cascade Reaction

Wei, W.-X.#; Li, Y.#; Wen, Y.-T.; Li, M.; Li, X.-S.; Wang, C.-T.; Liu, H.-C.; Xia, Y.; Zhang, B.-S.; Jiao, R.-Q.; Liang, Y.-M*

J. Am. Chem. Soc. 2021, 143 (20), 7868-7875.

22. Ruthenium-Catalyzed Radical Cyclization/meta-Selective C–H Alkylation of Arenes via σ-Activation Strategy

Gou, X.-Y.#; Li, Y.#; Luan, Y.-Y.; Shi, W.-Y.; Wang, C.-T.; An, Y.; Zhang, B.-S.; Liang, Y.-M.*

ACS Catal. 2021, 11 (7), 4263-4270.

21. Visible‐light‐Induced Sulfhydrylation and Oxylation of Olefins with Iodine as Catalyst

Ren, M.-Z., Yang, Y.-H., Zhu, Z.-H., Zhang, B.-S., Quan, Z.-J.* and Wang, X.-C.*

Asian J. Org. Chem. 2021, 10 (5),1067-1070.

20. Reductive Coupling of Aryl Halides via C‐H Activation of Indene.

Zhang, B.-S.*#; Yang, Y.-H.#; Wang, F.; Gou, X.-Y.; Wang, X.-C.*; Liang, Y.-M.*; Li, Y.*; Quan, Z.-J.*

Chin. J. Chem. 2021, 39 (6), 1573-1579.

2020

19. Synthesis of C4-Substituted Indoles via a Catellani and C–N Bond Activation Strategy.

Zhang, B.-S.*#; Wang, F.#; Yang, Y.-H.; Gou, X.-Y.; Qiu, Y.-F.; Wang, X.-C.; Liang, Y.-M.*; Li, Y.*; Quan, Z.-J.*

Org. Lett. 2020, 22 (21), 8267-8271.

18. DMAP and PivOH-promoted amination/allenization reaction.

Zhang, B.-S.; Li, Y.; Gou, X.-Y.; Zhang, Z.; An, Y.; Wang, X.-G.; Liang, Y.-M.*

Chem. Commun. 2020, 56 (64), 9202-9205.

Before NWNU

17. Synthesis of C4-Aminated Indoles via a Catellani and Retro-Diels–Alder Strategy.

Zhang, B.-S.; Li, Y.; Zhang, Z.; An, Y.; Wen, Y.-H.; Gou, X.-Y.; Quan, S.-Q.; Wang, X.-G.; Liang, Y.-M.*

J. Am. Chem. Soc. 2019, 141 (24), 9731-9738.

Hightlighted by CBG and huaxuejia.

16. Carboxylate Ligand-Exchanged Amination/C(sp3)–H Arylation Reaction via Pd/Norbornene Cooperative Catalysis.

Zhang, B.-S.; Li, Y.; An, Y.; Zhang, Z.; Liu, C.; Wang, X.-G.; Liang, Y.-M.*

ACS Catal. 2018, 8 (12), 11827-11833.

Hightlighted by Synfacts and X-MOL.

15. Three-component difluoroalkylation and trifluoromethylthiolation/trifluoromethylselenolation of π-bonds.

Zhang, B.-S.; Gao, L.-Y.; Zhang, Z.; Wen, Y.-H.; Liang, Y.-M.*

Chem. Commun. 2018, 54 (10), 1185-1188.

Hightlighted by Synfacts.

14. Palladium-catalyzed arene C–H activation/ketone C–H functionalization reaction: route to spirodihydroindenones.

Zhang, B.-S.; Hua, H.-L.; Gao, L.-Y.; Liu, C.; Qiu, Y.-F.; Zhou, P.-X.; Zhou, Z.-Z.; Zhao, J.-H.; Liang, Y.-M.*,

Org. Chem. Front. 2017, 4 (7), 1376-1379.

13. Visible-light-induced ligand-free RuCl3 catalyzed C–H phosphorylation in water.

Gou, X.-Y.#; Zhang, B.-S.#; Wang, X.-G.; Shi, W.-Y.; Liu, H.-C.; An, Y.; Zhang, Z.; Liang, Y.-M.*

Chem. Commun. 2020, 56, 4704-4707.

12. A carboxylate-assisted amination/unactivated C(sp2)–H arylation reaction via a palladium/norbornene cooperative catalysis.

An, Y.; Zhang, B.-S.; Zhang, Z.; Liu, C.; Gou, X.-Y.; Ding, Y.-N.; Liang, Y.-M.*

Chem. Commun. 2020, 56 (44), 5933-5936.

11. Palladium-Catalyzed Amination/Dearomatization Reaction of Indoles and Benzofurans.

Zhang, Z.; Zhang, B.-S.; Li, K.-L.; An, Y.; Liu, C.; Gou, X.-Y.; Liang, Y.-M.*

J. Org. Chem. 2020, 85 (12), 7817-7839.

10. Palladium-Catalyzed ortho-C–H Glycosylation/ipso-Alkenylation of Aryl Iodides.

Ding, Y.-N.; Shi, W.-Y.; Liu, C.; Zheng, N.; Li, M.; An, Y.; Zhang, Z.; Wang, C.-T.; Zhang, B.-S.; Liang, Y.-M.*

J. Org. Chem. 2020, 85 (17), 11280-11296.

9. Copper-Catalyzed Three-Component Redox-Neutral Ring Opening of Benzothiazoles to 1-Amino-N-(2-(phenylthio)phenyl)methanimine.

Zheng, N.; Liu, C.; Ding, Y.-N.; Shi, W.-Y.; Zhang, B.-S.; Liang, Y.-M.*

J. Org. Chem. 2020, 85 (12), 7666-7673.

8. Wang, X.-G.; Li, Y.; Liu, H.-C.; Zhang, B.-S.; Gou, X.-Y.; Wang, Q.; Ma, J.-W.; Liang, Y.-M.*

Three-Component Ruthenium-Catalyzed Direct meta-Selective C-H Activation of Arenes: A New Approach to The Alkylarylation of Alkenes.

J. Am. Chem. Soc. 2019, 141 (35), 13914–13922.

Hightlighted by X-MOL.

7. Synthesis of Difluoroalkyl Unsaturated β-Amino Acid Derivatives Exclusively through Alkyne Difunctionalization.

Wang, Q.; Jin, J.-N.; Chen, X.; Wang, X.-G.; Zhang, B.-S.; Ma, J.-W.; Liang, Y.-M.*

J. Org. Chem. 2018, 83 (23), 14626-14636.

6. Ruthenium-catalyzed ortho-selective CAr–H amination of heteroaryl arenes with di-tert-butyldiaziridinone.

Gou, X.-Y.; Li, Y.; Wang, X.-G.; Liu, H.-C.; Zhang, B.-S.; Zhao, J.-H.; Zhou, Z.-Z.; Liang, Y.-M.*

Chem. Commun. 2019, 55 (38), 5487-5490.

5. Ligand-controlled regiodivergent π-allyl palladium catalysis enables a switch between [3+2] and [3+3] cycloadditions.

Xia, Y.; Bao, Q.-F.; Li, Y.; Wang, L.-J.; Zhang, B.-S.; Liu, H.-C.; Liang, Y.-M.*

Chem. Commun. 2019, 55 (32), 4675-4678.

4. Ruthenium(ii)-catalyzed selective C–H difluoroalkylation of aniline derivatives with pyrimidyl auxiliaries

Wang, X.-G.; Li, Y.; Zhang, L.-L.; Zhang, B.-S.; Wang, Q.; Ma, J.-W.; Liang, Y.-M.,

Chem. Commun. 2018, 54 (68), 9541-9544.

3. Synthesis of indolines via a palladium/norbornene-catalyzed reaction of aziridines with aryl iodides.

Liu, C.; Liang, Y.; Zheng, N.; Zhang, B.-S.; Feng, Y.; Bi, S.; Liang, Y.-M.*

Chem. Commun. 2018, 54 (27), 3407-3410.

2. Copper-catalyzed difluoromethylation of propargylamide-substituted indoles: synthesis of mono- and bis-difluoromethylated indoloazepinone derivatives.

Hua, H.-L.; Zhang, B.-S.; He, Y.-T.; Qiu, Y.-F.; Hu, J.-Y.; Yang, Y.-C.; Liang, Y.-M.*,

Chem. Commun. 2016, 52 (68), 10396-10399.

1. Silver-Catalyzed Oxidative Cyclization of Propargylamide-Substituted Indoles: Synthesis of Phosphorated Indoloazepinones Derivatives.

Hua, H.-L.; Zhang, B.-S.; He, Y.-T.; Qiu, Y.-F.; Wu, X.-X.; Xu, P.-F.; Liang, Y.-M.*,

Org. Lett. 2016, 18 (2), 216-219.